Scrap-based Aluminium Alloys

About 100 Mt (million metric tons) of aluminum are currently produced per year, of which ~35% comes from scrap while ~40% has already been scrapped somewhere during preoduction. Aluminum reduces energy consumption in many products , e.g. in lightweight transport, packaging and construction, due to its low mass density (2.7 kg dm-3). It is also used for low-resistive, low-weight electrical conduction, as with 37×106 A (Vm)-1 it reaches 64% of the conductivity of pure Cu with about 3 times less mass. On the other hand, aluminum is also one of the greatest greenhouse gas (GHG) producers and energy-intensive industrial metals produced from ores.

Its GHG emissions include carbon dioxide, methane, nitrous oxides, hydrofluorocarbons, perfluorocarbons and sulphur hexafluoride. Globally, aluminum production contributes ~3% of all GHG emissions (~15% of all emissions in the industrial sector), with a ca. 1.1 Gt carbon dioxide equivalent per year.

This means that aluminum from primary production generates about 12-16.5 t of GHG per t of metal produced. About 65% of these emissions occur because ~67% of the electricity used for electrolysis is produced from fossil fuels. Aluminum production requires ~13 Exa J energy per year, which is ~1% of total global energy consumption. The synthesis of aluminum also creates multiple harmful by-products during mining and electrolysis. This impact is accelerating due to the rapid growth of the world population (and the enormous growth of the middle class, now estimated at half of the total population) and per-capita consumption of aluminum, which is driven by several current trends in transportation, urbanization, electrification and manufacturing. For the first time in history, though the production of aluminum is now facing sustainability limits. 

 

References:

Making sustainable aluminum by recycling scrap: The science of “dirty” alloys

 

Strategies for improving the sustainability of structural metals

 

How often can Aluminium be recycled?

Aluminum is in principle an infinitely recyclable material: today, about 75% of all the aluminum produced in history – nearly a billion metric tons – is still in use. Recycling involves re-melting the metal, which requires only 5% of the energy used to make new aluminum from bauxite ore: the primary synthesis of Al from ores expends 45 kWh/kg because of the large enthalpy of its oxide, and about 12 kg CO2/kg, while re-melting Al scrap (secondary synthesis) expends only 2.8 kWh/kg because of its low melting point (660°C), and about 0.6 kg CO2/kg. This means that recycling has the potential to shift aluminum’s energy and carbon balance substantially towards much greater sustainability.

On average, a third of the aluminum used today is produced from recycled scrap, although this fraction is predicted to rise to 50% by 2050, according to recent data (2019) from the International Aluminum Institute. The huge differences between primary and secondary synthesis in terms of GHG and energy consumption make aluminum alloys, as an important pillar of a circular economy, important subjects for sustainable metallurgy research.

In scrap recycling a differentiation must be made between pre-consumer scrap, produced during manufacturing and often featuring well-defined alloy classification, and mixed, low-quality post-consumer scrap, which must be sorted before remelting.